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Face Pigmentation: The most apparent reason for pigmentation on the face is exposure to the sun. The harsh UV rays result in up to 80% of signs of premature aging, out of which one is hyper pigmentation that can be seen in the form of age spots caused due to prolonged exposure. Produced by skin cells called melanocytes, melanin is a pigment due to which skin gets its color. Excess production of melanin can lead to pigmentation on the face. An underlying condition like Addison's disease can also cause pigmentation. For more details, Watch Video.